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Thermodynamic study on dynamic water and organic vapor sorption on amorphous valnemulin hydrochloride

Jinbo OUYANG, Jingkang WANG, Yongli WANG, Qiuxiang YIN, Hongxun HAO

Frontiers of Chemical Science and Engineering 2015, Volume 9, Issue 1,   Pages 94-104 doi: 10.1007/s11705-015-1460-3

Abstract: The sorption of water and organic vapors on valnemulin hydrochloride was determined by dynamic vaporThe adsorption-desorption behavior of water vapor and a series of organic vapors was investigated to

Keywords: valnemulin hydrochloride     water vapor     organic vapors     sorption     kinetics    

Upgrading of derived pyrolysis vapors for the production of biofuels from corncobs

Liaoyuan Mao, Yanxin Li, Z. Conrad Zhang

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 1,   Pages 50-58 doi: 10.1007/s11705-017-1685-4

Abstract: pyrolyzed in the bubbling bed using fine sand particles as a heat carrier and the resulting pyrolysis vapors

Keywords: corncob     monolith     upgrading     pyrolysis    

The prediction of adsorption isotherms of ester vapors on hypercrosslinked polymeric adsorbent

Liuyan WU,Lijuan JIA,Xiaohan LIU,Chao LONG

Frontiers of Environmental Science & Engineering 2016, Volume 10, Issue 3,   Pages 482-490 doi: 10.1007/s11783-015-0826-6

Abstract: Adsorption isotherms of methyl acetate, ethyl acetate, propyl acetate, isopropyl acetate and ethyl propionate on hypercrosslinked polymeric resin (ND-100) were measured at 303K, 318K and 333K,respectively, and well fitted by Dubinin–Astakhov (DA) equation. The plots of the adsorbed volume ( ) versus the adsorption potential ( ) at three different temperatures all fell basically onto one single curve for every ester. A predicted model based on DA equation was obtained on the basis of adsorption equilibrium data of methyl acetate, ethyl acetate and ethyl propionate at 318K. The model equation successfully predicted the adsorption isotherms of methyl acetate, ethyl acetate and ethyl propionate on ND-100 at 303K, and 333K, and also gave accurate predictive results for adsorption isotherms of the other two ester compounds (propyl acetate and isopropyl acetate) on ND-100 at 303K, 318K and 333K. The results proved the effectiveness of DA model for predicting the adsorption isotherms of ester compounds onto ND-100. In addition, the relationship between physico-chemical properties of adsorbates and their adsorption properties was also investigated. The results showed that molecular weight, molar volume and molar polarizability had good linear correlations with the parameter (which represents adsorption characteristic energy) of DA equation.

Keywords: hypercrosslinked polymeric adsorbent     adsorption isotherm     ester     prediction    

Hierarchical porous metal-organic frameworks/polymer microparticles for enhanced catalytic degradationof organic contaminants

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 6,   Pages 939-949 doi: 10.1007/s11705-022-2152-4

Abstract: microparticles containing hierarchical porous structures integrated with highly accessible catalytic metal organicframeworks for efficient degradation of organic contaminants.possess interconnected hierarchical porous structures decorated with highly accessible Fe-based metal-organicframework nanorods for enhanced degradation of organic contaminants via a heterogeneous Fenton-likesimple and general strategy to flexibly combine hierarchical porous structures and catalytic metal-organic

Keywords: metal-organic framework     polymer microparticle     nanocatalyst     decontamination     organic contaminant    

Enhancing the adsorption function of biochar by mechanochemical graphitization for organic pollutant

Frontiers of Environmental Science & Engineering 2021, Volume 15, Issue 6, doi: 10.1007/s11783-021-1418-2

Abstract:

• Mechanochemical treatment reduced the calcination temperature for biochar synthesis.

Keywords: Biochar     Mechanochemical treatment     Graphitization     Calcination temperature     Organic pollutant    

Dynamic response surface methodology using Lasso regression for organic pharmaceutical synthesis

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 2,   Pages 221-236 doi: 10.1007/s11705-021-2061-y

Abstract: DRSM with Lasso regression can provide faster and more accurate data-driven models for a variety of organic

Keywords: data-driven modeling     pharmaceutical organic synthesis     Lasso regression     dynamic response surface methodology    

Construction of MOFs-based nanocomposite membranes for emerging organic contaminants abatement in water

Frontiers of Environmental Science & Engineering 2023, Volume 17, Issue 7, doi: 10.1007/s11783-023-1689-x

Abstract:

● Application of the MOF-composite membranes in adsorption was discussed.

Keywords: Emerging organic contaminants     Metal organic frameworks     Synthesis     Adsorption     Catalysis    

Characterization and comparison of organic functional groups effects on electrolyte performance for vanadium

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 9,   Pages 1221-1230 doi: 10.1007/s11705-023-2298-8

Abstract: electrolyte energy density and stability limitations, as well as to investigate the effects of various organic

Keywords: vanadium redox flow battery     functional groups     organic additives     energy density     stability    

Exposure-response of Cr(III)-organic complexes to Saccharomyces cerevisiae

Nivedita CHATTERJEE, Zejiao LUO,

Frontiers of Environmental Science & Engineering 2010, Volume 4, Issue 2,   Pages 196-202 doi: 10.1007/s11783-010-0008-5

Abstract: Hexavalent chromium [Cr(VI)] bioreduction produces soluble Cr(III)-organic complexes.The Cr(III)-organic complexes are relatively stable once they are formed, and no data about their toxicityTherefore, this study aims to investigate the bioavailability and toxicity of the soluble Cr(III)-organicas the model organism and Cr(III)-citrate was selected as the representative compound of the Cr(III)-organic

Keywords: Cr(III)-organic complexes     Saccharomyces cerevisiae     toxicity     EC50     bioavailability    

Environmental effects and risk control of antibiotic resistance genes in the organic solid waste aerobic

Frontiers of Environmental Science & Engineering 2021, Volume 15, Issue 6, doi: 10.1007/s11783-021-1415-5

Abstract:

• ARGs were detected in livestock manure, sludge, food waste and fermentation dregs.

Keywords: Antibiotic resistance genes     Organic solid waste     Aerobic composting     Livestock manure     Sludge    

Metal-organic framework UiO-66 membranes

Xinlei Liu

Frontiers of Chemical Science and Engineering 2020, Volume 14, Issue 2,   Pages 216-232 doi: 10.1007/s11705-019-1857-5

Abstract: Metal-organic frameworks (MOFs) have emerged as a class of promising membrane materials.

Keywords: membrane     metal-organic framework     UiO-66     separation    

Photoaging mechanism of microplastics: a perspective on the effect of dissolved organic matter in natural

Frontiers of Environmental Science & Engineering 2023, Volume 17, Issue 11, doi: 10.1007/s11783-023-1743-8

Abstract:

● Microplastics (MPs) undergo photoaging in natural water under light irradiation.

Keywords: Microplastics     Photoaging     Dissolved organic matter     ROS generation    

Metal-organic frameworks for CO

Lei ZHANG, Junqing ZHANG

Frontiers in Energy 2019, Volume 13, Issue 2,   Pages 221-250 doi: 10.1007/s11708-019-0629-8

Abstract: Metal-organic frameworks (MOFs) have attracted much attention because of their large surface areas, tunable

Keywords: metal-organic frameworks (MOFs)     photocatalysis     CO2 photoreduction     composite    

Review of plasma-assisted reactions and potential applications for modification of metal–organic frameworks

Tingting Zhao, Niamat Ullah, Yajun Hui, Zhenhua Li

Frontiers of Chemical Science and Engineering 2019, Volume 13, Issue 3,   Pages 444-457 doi: 10.1007/s11705-019-1811-6

Abstract: involved in dry reforming of methane, CO methanation, the methane coupling reaction, and volatile organicApplications of plasma for modification of metal–organic frameworks are discussed.

Keywords: plasma catalysis     methane     carbon dioxide     VOCs     metal–organic frameworks    

Predictive models on photolysis and photoinduced toxicity of persistent organic chemicals

Qing ZHANG

Frontiers of Environmental Science & Engineering 2013, Volume 7, Issue 6,   Pages 803-814 doi: 10.1007/s11783-013-0547-7

Abstract: The data on photodegradation kinetics and photoinduced toxicities of organic chemicals are essentialstructure-activity relationship (QSAR) models that relate photodegradation kinetics or photoinduced toxicity of organicThis paper reviews the QSAR models on photodegradation quantum yields and rate constants for toxic organicliquid phase, gaseous phase, surfaces of plant leaves, and QSAR models on photoinduced toxicity of organicprospects for QSAR model development on photodegradation kinetics and photoinduced toxicity of refractory organic

Keywords: quantitative structure-activity relationship (QSAR) models     photodegradation     persistent organic pollutants    

Title Author Date Type Operation

Thermodynamic study on dynamic water and organic vapor sorption on amorphous valnemulin hydrochloride

Jinbo OUYANG, Jingkang WANG, Yongli WANG, Qiuxiang YIN, Hongxun HAO

Journal Article

Upgrading of derived pyrolysis vapors for the production of biofuels from corncobs

Liaoyuan Mao, Yanxin Li, Z. Conrad Zhang

Journal Article

The prediction of adsorption isotherms of ester vapors on hypercrosslinked polymeric adsorbent

Liuyan WU,Lijuan JIA,Xiaohan LIU,Chao LONG

Journal Article

Hierarchical porous metal-organic frameworks/polymer microparticles for enhanced catalytic degradationof organic contaminants

Journal Article

Enhancing the adsorption function of biochar by mechanochemical graphitization for organic pollutant

Journal Article

Dynamic response surface methodology using Lasso regression for organic pharmaceutical synthesis

Journal Article

Construction of MOFs-based nanocomposite membranes for emerging organic contaminants abatement in water

Journal Article

Characterization and comparison of organic functional groups effects on electrolyte performance for vanadium

Journal Article

Exposure-response of Cr(III)-organic complexes to Saccharomyces cerevisiae

Nivedita CHATTERJEE, Zejiao LUO,

Journal Article

Environmental effects and risk control of antibiotic resistance genes in the organic solid waste aerobic

Journal Article

Metal-organic framework UiO-66 membranes

Xinlei Liu

Journal Article

Photoaging mechanism of microplastics: a perspective on the effect of dissolved organic matter in natural

Journal Article

Metal-organic frameworks for CO

Lei ZHANG, Junqing ZHANG

Journal Article

Review of plasma-assisted reactions and potential applications for modification of metal–organic frameworks

Tingting Zhao, Niamat Ullah, Yajun Hui, Zhenhua Li

Journal Article

Predictive models on photolysis and photoinduced toxicity of persistent organic chemicals

Qing ZHANG

Journal Article